PROCESSES OCCURRING IN BREAD DURING ITS BAKING
Prof. A. Ya. Auermann. 1942 year
1.1 Warming up the dough-bread
Bread products are baked in the baking chamber of a baking oven at an air-vapor temperature of 200-280 ° C. Baking 1 kg of bread requires about 293-544 kJ. This heat is mainly spent on evaporation of moisture from the dough piece and on heating it to a temperature of 96-97 ° C in the center, at which the dough turns into bread. A large proportion of heat (80-85%) is transferred to the dough-bread by radiation from the hot walls and arches of the baking chamber. The rest of the heat is transferred by conduction from the hot hearth and by convection from the moving currents of the steam-air mixture in the baking chamber.
The dough pieces are heated gradually, starting from the surface, therefore, the processes typical for baking do not take place simultaneously in the entire mass of bread, but in layers - first in the outer layers, then in the inner layers. The speed of heating the dough-bread as a whole, and, consequently, the duration of baking depends on a number of factors. As the temperature in the baking chamber rises, the workpieces are heated faster and the baking time is shortened. Dough with high moisture content and porosity heats up faster than strong and dense dough.
Dough pieces of significant thickness and weight, all other things being equal, heat up longer. Shaped bread is baked more slowly than hearth bread. The tight fit of the dough pieces on the bottom of the oven slows down the baking of the products.
1.2 Formation of a hard bread crust
This process occurs as a result of dehydration of the outer layers of the dough piece. It is important to note that the hard crust stops the growth of the dough and bread volume, and therefore the crust should not form immediately, but 6-8 minutes after the start of baking, when the maximum volume of the piece has already been reached.
For this purpose, steam is supplied to the first zone of the baking chamber, the condensation of which on the surface of the workpieces delays dehydration of the top layer and the formation of a crust. However, after a few minutes, the top layer, warming up to a temperature of 100 ° C, begins to quickly lose moisture and at a temperature of 110-112 ° C turns into a thin crust, which then gradually thickens.
When the crust is dehydrated, part of the moisture (about 50%) evaporates into the environment, and part passes into the crumb, since when various materials are heated, moisture always passes from the more heated areas (crust) to less heated areas (crumb). The moisture content of the crumb as a result of the movement of moisture from the crust increases by 1.5-2.5%. By the end of baking, the moisture content of the crust is only 5–7%, which means that the crust is practically dehydrated.
The temperature of the crust reaches 160-180 ° C by the end of baking. Above this temperature, the crust does not heat up, since the heat supplied to it is spent on moisture evaporation, overheating of the resulting steam, and also on crumb formation.
The following processes take place in the surface layer of the workpiece and in the crust: gelatinization and dextrinization of starch, denaturation of proteins, formation of aromatic and dark-colored substances and removal of moisture. In the first minutes of baking, as a result of steam condensation, starch on the surface of the workpiece is gelatinized, partially passing into soluble starch and dextrins. A liquid mass of soluble starch and dextrins fills the pores located on the surface of the workpiece, smoothes out minor irregularities and, after dehydration, gives the crust a shine and gloss.
Denaturation of protein substances on the surface of the product occurs at a temperature of 70-90 ° C. Protein coagulation, along with dehydration, contributes to the formation of a dense, inelastic crust. Until a certain time, the color of the crust of bread was associated with the amount of residual, unfermented sugars in the dough at the time of baking. For a normal color of the crust, the dough before baking must contain at least 2-3% unfermented sugars. The higher the sugar and gas forming ability of the dough, the more intense the color of the bread crust.
Previously, it was believed that the products that determine the color of the crust of bread are brown-colored products of caramelization or primary hydration of residual dough sugars not fermented at the time of baking. Caramelization and dehydration of sugars in the crust was explained by its high temperature. Some researchers believe that colored products of thermal dextrinization of starch and thermal changes in protein substances of the crust play a role in the color of the crust.
Based on a number of studies, it can be assumed that the intensity of the color of the bread crust is mainly due to the formation in it of dark-colored products of the redox interaction of residual, unfermented reducing dough sugars and protein proteolysis products contained in the dough, that is, melanoidins. In addition, the color of the crust depends on the baking time and the temperature in the baking chamber.
1.3 Internal movement of moisture in bread
When baking, the moisture content of the inside of the bread changes. An increase in the moisture content of the outer layers of a baked product in the initial phase of baking with a strong humidification of the gaseous environment of the baking chamber and a subsequent decrease in the moisture content of the surface layer to equilibrium moisture, which occurs as this layer turns into a crust, were noted above. In this case, not all the moisture evaporating in the baked bread in the evaporation zone passes in the form of steam through the pores of the crust into the baking chamber.
The crust is much more compact and much less porous than the crumb. The pore size in the crust, especially in its surface layer, is many times smaller than the pore size in the adjacent crumb layers. As a result, the crust of bread is a layer that offers great resistance to steam passing through it from the evaporation zone into the baking chamber. Part of the steam generated in the evaporation zone, especially above the bottom crust of the bread, can rush out of it through the pores and crumb holes into the crumb layers adjacent to the evaporation zone from the inside. Reaching the layers located closer to the center and less heated, water vapor condenses, thereby increasing the moisture content of the layer in which the condensation has occurred.
This crumb layer, which is, as it were, a zone of internal condensation of water vapor in baked bread, corresponds to the configuration of isothermal surfaces in bread. For the internal movement of moisture in a wet material, there must be a difference in transfer potential. In baked dough bread, there can be two main reasons for moisture transfer: a) the difference in moisture concentration in different parts of the product and b) the difference in temperature in individual parts of the dough bread.
The difference in moisture concentration is an incentive to move moisture in the material from areas with a higher moisture concentration to areas with a lower moisture concentration. Such movement is conventionally called concentration (concentration diffusion or concentration moisture conductivity).
Temperature differences in individual areas of wet material also cause moisture to move from areas of the material with a higher temperature to areas with a lower temperature. This movement of moisture is conventionally called thermal.
In baked bread, both a large difference in the moisture content of the crust and crumb and a significant temperature difference between the outer and central layers of the bread during the first baking period are observed.As the works of domestic researchers have shown, when baking bread, the stimulating effect of the temperature difference in the outer and inner layers prevails, and therefore the moisture in the crumb during the baking process moves from the surface to the center.
Experiments show that the moisture content of the crumb of bread in the baking process increases by about 2% compared to the original moisture content of the dough. Moisture increases most rapidly in the outer layers of the crumb during the initial period of the baking process, which is explained by the large role of thermal and moisture conductivity in this period of baking due to the significant temperature gradient in the crumb.
From a number of works it follows that during baking, the moisture content of the surface layer of a piece of dough quickly drops and very quickly reaches the level of equilibrium moisture content, due to the temperature and relative humidity of the steam-air mixture. Deeper layers and later turning into a crust layer more slowly reach the same equilibrium moisture content.
1.4 Crumbling
When baking inside the dough piece, fermentative microflora is suppressed, enzyme activity changes, starch gelatinization and thermal denaturation of proteins occur, humidity and temperature of the inner layers of the dough-bread change. The vital activity of yeast and bacteria in the first minutes of baking increases, as a result of which alcohol and lactic acid fermentation is activated. At 55-60 ° C, yeast and non-thermophilic lactic acid bacteria die off.
As a result of the activation of yeast and bacteria at the beginning of baking, the content of alcohol, carbon monoxide and acids slightly increases, which has a positive effect on the volume and quality of the bread. The activity of enzymes in each layer of the baked product first increases and reaches a maximum, and then drops to zero, since enzymes, being protein substances, coagulate when heated and lose the properties of catalysts. The activity of a-amylase can have a significant effect on the quality of the product, since this enzyme is relatively resistant to heat.
In rye dough, which is highly acidic, a-amylase is destroyed at a temperature of 70 ° C, and in wheat dough only at temperatures above 80 ° C. If the dough contains a lot of a-amylase, then it will convert a significant part of the starch into dextrins, which will degrade the quality of the crumb. Proteolytic enzymes in bread doughs are inactivated at 85 ° C.
A change in the state of starch, together with changes in protein substances, is the main process that turns the dough into bread crumb; they happen almost simultaneously. Starch grains gelatinize at temperatures of 55-60 ° C and above. Cracks form in the starch grains, into which moisture penetrates, which is why they increase significantly. During gelatinization, starch absorbs both the free moisture of the dough and the moisture released by the curdled proteins. Starch gelatinization occurs when there is a lack of moisture (for complete starch gelatinization, the dough must have 2-3 times more water), there is no free moisture left, so the crumb of the bread becomes dry and non-sticky to the touch.
The moisture content of the crumb of hot bread (in general) rises by 1.5-2% compared to the moisture content of the dough due to moisture transferred from the upper layer of the workpiece. Due to the lack of moisture, starch gelatinization is slow and ends only when the central layer of the dough is heated to a temperature of 96-98 ° C. The temperature of the center of the crumb does not rise above this value, since the crumb contains a lot of moisture, and the heat supplied to it will not be spent on heating the mass, but on its evaporation.
When baking rye bread, not only gelatinization occurs, but also acid hydrolysis of a certain amount of starch, which increases the content of dextrins and sugars in dough bread. Moderate hydrolysis of starch improves the quality of the bread.
The change in the state of protein substances begins at a temperature of 50-70 ° C and ends at a temperature of about 90 ° C.Protein substances in the baking process undergo thermal denaturation (coagulation). At the same time, they become denser and release moisture absorbed by them during the formation of the dough. Curdled proteins fix (fix) the porous structure of the crumb and the shape of the product. A protein framework is formed in the product, into which grains of swollen starch are interspersed. After thermal denaturation of proteins in the outer layers of the product, the increase in the volume of the workpiece stops.
The final moisture content of the inner surface of the layer adjacent to the crumb can be taken approximately equal to the initial moisture content of the dough (W0) plus an increase due to the internal movement of moisture (W0 + DW), while the outer surface of this layer adjacent to the crust has a moisture content equal to equilibrium humidity. Based on this, on the graph for this layer, the value of the final moisture content is taken, the average between the values (W0 + DW) and W0Р.
The moisture content of the individual layers of the crumb also increases during the baking process, and the increase in moisture occurs first in the outer layers of the crumb, then captures more and more deeply located layers. As a result of the thermal movement of moisture (thermal moisture conductivity), the moisture content of the outer layers of the crumb, closer to the evaporation zone, even begins to decrease somewhat against the maximum reached. However, the final moisture content of these layers is still higher than the original moisture content of the dough when baking starts. The moisture in the center of the crumb builds up the slowest, and its final moisture may be slightly less than the final moisture in the layers adjacent to the center of the crumb.
1.5 Vital activity of the fermenting microflora of the dough during the baking process
The vital activity of the fermenting microflora of the dough (yeast cells and acid-forming bacteria) changes as a piece of dough-bread heats up during the baking process.
When the dough is heated to about 35 ° C, yeast cells accelerate the fermentation and gas formation process they cause to a maximum. Up to approx. 40 ° C, the yeast activity in the baked dough is still very intense. When the dough is heated to a temperature above 45 ° C, gas formation caused by the yeast is sharply reduced.
Previously, it was believed that at a dough temperature of about 50 ° C, yeast dies off.
The vital activity of the acid-forming microflora of the dough, depending on the temperature optimum (which is about 35 ° C for non-thermophilic bacteria, and about 48-54 ° C for thermophilic bacteria), is first forced as the dough warms up, and then, after reaching the temperature above the optimum, it stops.
It was believed that when the dough is heated to 60 ° C, the acid-forming flora of the dough completely dies off. However, the work carried out by a number of researchers suggests that in the crumb of ordinary rye bread made from wallpaper flour, although in a weakened, but viable state, individual cells of both yeast and acid-forming bacteria are preserved.
From the fact that a small part of the viable fermentative microflora of the dough is retained in the crumb of bread during baking, it does not in any way follow that fermentative microorganisms can, under all conditions, withstand the temperature of 93-95 ° C, which is reached in the center of the bread during baking.
It was also shown that boiling the crumb of bread, pounded in excess water, killed all types of fermentative microorganisms.
Obviously, the preservation of a part of the fermenting microflora of the dough in the crumb of bread in a viable state can be explained by both a very small amount of free water and a very short-term rise in the temperature of its central part above 90 ° C.
From the above data, it follows that the temperature optima for the fermenting microflora of the dough, determined under the conditions of the environment, in consistency different from the dough, may be underestimated in comparison with the optima acting under the conditions of the baked dough-bread.
Obviously, it should be considered that when the dough is heated to about 60 ° C, the vital activity of yeast and non-thermophilic acid-forming bacteria of the dough practically stops. Thermophilic lactic acid bacteria such as Delbrück bacteria can be fermentatively active even at higher temperatures (75-80 ° C).
The changes described above in the vital activity of the fermenting microflora of the baked piece of dough occur gradually, as it warms up, spreading from the surface layers to the center.
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